Finite element method based investigation of substrates effect on surface-enhanced Raman spectroscopy

A. Adiraju, A. Al-Hamry, O. Kanoun
Abstract:
Surface-enhanced Raman spectroscopy (SERS) is a widely used method for the detection of molecules of environmental concern such as pesticides. One of the key factors to achieve high sensitivity in SERS is the high electromagnetic enhancement formed between plasmonic nanoparticles which is dependent on the wavelength used, shape, size, distance, and type of nanoparticles. In this regard, the scope of this paper is to investigate the enhancement factor achieved between adjacent silver or gold nanoparticles of different geometrical configurations by changing the shapes and sizes of the particles. Simulations based on finite element methods (FEM) were carried out to investigate the effect of different excitation laser wavelengths. The obtained results show the dependency of the enhancement factor, size, type of nanoparticles, excitation wavelength of the laser, dielectric properties of the surrounding medium and the type of substrate used.
Keywords:
SERS; FEM; plasmonics; metals; COMSOL
Download:
IMEKO-TC19-2022-12.pdf
DOI:
10.21014/tc19-2022.12
Event details
IMEKO TC:
TC19
Event name:
TC19 Symposium: Metrology on Environmental Instrumentation and Measurements (EnvIMEKO 2022)
Title:

9th EnvIMEKO Symposium of Environmental Instrumentation and Measurements

Place:
La Mans, FRANCE
Time:
02 June 2022 - 03 June 2022